逍遥学能 2018-01-13 21:21
Ac Acetyl
DMAP 4-dimethylaminopyridine
acac Acetylacetonate
DME dimethoxyethane
AIBN Azo-bis-isobutryonitrile
DMF N,N’-dimethylformamide
aq. Aqueous
dppf bis (diphenylphosphino)ferrocene
9-BBN 9-borabicyclo[3.3.1]nonane
dppp 1,3-bis (diphenylphosphino)propane
BINAP (2R,3S)-2,2’-bis (diphenylphosphino)-1,1’-binaphthyl
dvb Divinylbenzene
Bn Benzyl
e- Electrolysis
BOC t-butoxycarbonyl
î % enantiomeric excess
Bpy (Bipy) 2,2’-bipyridyl
EDA (en) ethylenediamine
Bu n-butyl
EDTA Ethylenediaminetetraacetic acid
Bz Benzoyl
EE 1-ethoxyethyl
c- Cyclo
Et Ethyl
CAM Carboxamidomethyl
FMN Flavin mononucleotide
CAN Ceric ammonium nitrate
fod Tris-(6,6,7,7,8,8,-heptafluoro-2,2-dimethyl-3,5-octanedionato
Cat. Catalytic
Fp flash point OR Cyclopentadienyl-bis -carbonyl iron
CBz Carbobenzyloxy
FVP Flash vacuum pyrolysis
Chirald (2S,3R)-(+)-4-dimethylamino-1,2-diphenyl-3-methylbutan-2-ol
h hours
COD 1,5-Cylcooctadienyl
hv Irradiation with light
COT 1,3,5-cyclooctatrienyl
1,5-HD 1,5-hexadienyl
Cp Cyclopentadienyl
HMPA Hexamethylphosphoramide
CSA 10-camphorsulfonic acid
HMPT Hexamethylphosphorus triamide
CTAB Cetyltrimethylammonium bromide
iPr isopropyl
Cy Cyclohexyl
LAH Lithium aluminum hydride
DABCO 1,4-diazabicyclo[2.2.2]octane
LDA Lithium diisopropylamide
dba Dibenzylidene acetone
LHMDS Lithium hexamethyldisilazide
DBE 1,2-dibromoethane
LTBA Lithium tri-tert-butoxyaluminum hydride
DBN 1,8-diazabicyclo[5.4.0]undec-7-ene
mCPBA meta-cholorperoxybenzoic acid
DBU 1,5-diazabicyclo[4.3.0]non-5-ene
Me Methyl
DCC 1,3-dicyclohexylcarbodiimide
MEM b-methoxyethoxymethyl
DCE 1,2-dichloroethane
Mes Mesityl
DDQ 2,3-dichloro-5,6-dicyano-1,4-benzoquinone
Min Minute
Þ % diasteromeric excess
MOM methoxymethyl
DEA Diethylamine
Ms Methanesulfonyl
DEAD Diethyl azodicarboxylate
MS Molecular sieves (3 or 4 ?)
Dibal-H Diisobutylaluminum hydride
MTM Methylthiomethyl
diphos (dppe) 1,2-bis (diphenylphosphino)ethane
Naphth Naphthyl
diphos-4 (dppb) 1,4-bis (diphenylphosphino)butane
NBD Norbornadiene
NBS N-Bromosuccinimide
TASF Tris(diethylamino)sulfonium difluorotrimethyl silicate
NCS N-chlorosuccinimide
TBAF Tetrabutylammonium fluoride
Ni(R) Raney Nickel
TBDMS, TBS t-butyldimethylsilyl
NMO N-methyl morpholine-n-oxide
TBHP t-butylhydroperoxide
PCC Pyridinium chlorochromate
t-Bu Tert-butyl
PDC Pyridinium dichromate
TEBA Triethylbenzylammonium
PEG Polyethylene glycol
TEMPO Tetramethylpiperdinyloxy free radical
Ph Phenyl
TFA Trifluoroacetic acid
PhH Benzene
TFAA Trifluoroacetic anhydride
PhMe Toluene
Tf or OTf Triflate
Phth Phthaloyl
THF Tetrahydrofuran
Pip Piperidyl
THP Tetrahydropyranyl
Pr n-propyl
TMEDA Tetramethylethylenediamine
Py Pyridine
TMP 2,2,6,6-tetramethylpiperidine
quant. quantitative yield
TMS Trimethylsilyl
Red-Al [(MeOCH2CH2O)AlH2]Na
Tol Tolyl
sBu sec-butyl
Tr Trityl
sBuLi sec-butyllithium
TRIS Triisopropylphenylsulfonyl
Siamyl Diisoamyl
Ts (Tos) Tosyl (p-toluenesulfonyl)